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Chemical and Freezing Temps

So early this winter we did a garage clean out/organization day and my wife put my tote of chemical in our outdoor storage area and I hadn't noticed until now. No protection from the temps. Will this affect their effectiveness, potency, etc? It was gly, 2-4-D, liquid AMS and surfactant. Thoughts? Am I safe, or safer to just replace it all?
 
I’ve never had an issue with storage of those things. I could be wrong but I think u r just fine using them.
 
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